|
Purification
technologies
The
purity level of water supplied by a point-of-use water system can be
measured by contaminant levels in five main categories: inorganics,
organics, bacteria, pyrogens, and nucleases and DNA. Purification
technologies Once the system requirements have been determined, you
can select purification technologies that are capable of meeting
these requirements.
Deionization
is the most widely accepted method for producing high-purity reagent
grade water. This process removes the ionic contaminants from the
water.
Distillation
is the broadest contaminant-removal technology. This process removes
the water from the contaminants.
Reverse
osmosis is more commonly used for pretreatment of water systems.
Ultraviolet
oxidation controls organics and bacteria, and it is often used in
concert with filtration. Filtration can be employed as pre-, post-,
or ultra-filtration. All have merits for removing particles,
bacteria, and pyrogens. Adsorption is typically used to remove
organics, chlorine, and ozone.
Each
purification technology has distinct capabilities and limitations.
Deionization is dissolved-ion specific, whereas distillation is
boiling point specific. With distillation, any-thing with a higher
boiling point than water will be removed, but anything with a lower
boiling point will carry over into the distillate. Chlorine is one
significant element that can carry over, and if this is a problem,
water being purified by distillation should be pre-treated with
carbon before the distillation step. Reverse osmosis can be a useful
tool, but keep in mind that it’s a percent removal technology. It
typically works best in a pretreatment setting, or in combination
with other purification technologies.
|
Table
1. Devices for Disinfection of Water
Type Advantages Limitations Special Requirements
|
|
Type
|
Advantages
|
Limitations
|
Special Requirements
|
|
Ceramic Candles
|
Inexpensive, simple
|
May not be effective against viruses
|
none
|
|
Chlorination
|
Proven technology
|
May require additional filters to remove protozoan cysts
|
Residual test kit, electricity
|
|
Distillation
|
Effective against all pathogens
|
Batch system - water may not be available when required
|
Electricity
|
|
Iodination
|
Inexpensive
|
May require additional filters to remove cysts. Possible
physiological effects of iodine
|
Residual test kit
|
|
Ozonation
|
Low operating cost
|
May require additional filters to remove cysts. Iron,
suphur and manganese must not be excessive
|
Electricity
|
|
UltraViolet Light
|
Uses no chemicals
|
May require additional filters to remove cysts. May be
only partially effective if water is turbid
|
Electricity, UV monitor
|
|
Table
2. Devices for Taste, Odour and Chemical Removal
|
|
Type
|
Advantages
|
Limitations
|
Special Requirements
|
|
Activated Carbon
|
Removes taste, odour, organics, chlorine, low levels of
hydrogen sulphide
|
Should be used on microbiologically sage water
|
Cartridges should be changed regularly
|
|
Chlorination
|
Iron, manganese, hydrogen sulphide removal
|
Quantity used must be accurate
|
Electricity, filter to remove precipitates
|
|
Distillation
|
Removes inorganic salts, some organic chemicals,
particles, hydrogen sulphide
|
May concentrate some organic chemicals
|
Electricity
|
|
Greensand Filters
|
Iron, manganese, hydrogen sulphide removal
|
May clog or reduce effectiveness due to bacterial growth
|
Backwash and regenerate regularly, replace media
|
|
Particulate Filters
|
Turbidity, particle removal
|
May clog or reduce effectiveness due to bacterial growth
|
Regular changing / cleaning
|
|
Reverse Osmosis
|
Inorganic salts removal
|
Susceptible to clogging
|
Adequate water pressure, flushing
|
|
Softeners
|
Hardness (calcium, magnesium) removal
|
Elevates sodium content; possible bacteria growth
|
Usually require electricity
|
Click
here for a list of the
National
Primary Drinking Water Regulations
For
the technically minded more details are provided on some water
purification technologies.
1. Reverse Osmosis
2. Ozonation
3.Ultraviolet lamps
Point
of use Reverse Osmosis drinking water systems
Reverse Osmosis is a membrane separation process in which feed
water flows along the membrane surface under pressure. Purified
water permeates through the membrane and is collected in a storage
tank while the concentrated water, containing dissolved and
undissolved material that does not flow through the membrane, is
discharged to the drain.
Compared with other conventional water treatment processes,
Reverse Osmosis has proven to be the most efficient means of
removing salts, chemical contaminants and heavy metals, such as
lead, from drinking water.
A
Typical 3 stage reverse osmosis is installed beneath your kitchen
sink and Includes a sediment prefilter, membrane, carbon post
filter, 3 gallon storage tank and separate faucet. The water first
flows through a sediment prefilter, which removes suspended solids
and helps protect the membrane. Next, it enters the reverse osmosis
membrane, that allows the pure water molecules to pass but rejects
dissolved solids like sodium and impurities like lead, arsenic and
nitrates etc. The rejection water is then washed down the kitchen
drain. leaving only The purified water that stored in a small
storage tank until it is needed. When the separate faucet mounted on
the sink is opened, the purified water is forced by air pressure
through a post carbon filter, which gives the water a final polish
for great tasting water. Additional filters can be added to the RO
unit.
Typical Rejection
Characteristics of Reverse Osmosis
You may or may not have these
contaminants in your water. The percentage rejection rate is for
reference only. Percentages may vary since water chemistry varies in
each water supply.
Hydrocarbons, Proteins, Pesticides,
Herbicides, Insecticides, Trichlorethylene & THMs (chlorine
by-products) will be rejected at 90% or greater Rejection rates are based upon
Cellulose membrane usage. Expect slightly higher rejection rates
with TFC membrane usage.
Never use a Reverse Osmosis System on
water that is microbiologically unsafe. Reverse Osmosis should not
be solely relied upon for total contamination removal.
Nitrates
Nitrates
can be found in water supplies that are in areas where there are
heavy use of fertilizers. Nitrates can cause Methemoglobinemia
a.k.a. blue baby syndrom. This is a serious condition in young
infants and new born animals where the oxygen carrying capacity of
the blood is reduced.
|
Nitrates
above 10.0ppm (EPA limit for drinking water) is considered a
hazard
|
Lead
Lead in your water can be caused by metal plating pollution
or corrosion from your piping.
Pesticides,
Herbicides & Insecticides
These problems can be due to excessive agricultural spraying and water
run off in to water supplies
Why Use Ozone?
Ozone is rapidly emerging as the most efficient and
ecologically sound oxidant to treat both organic and inorganic
substances. A fast-acting and effective treatment technology, ozone
is now used in a variety of water treatment applications. Best known
for its superior disinfection capability, ozone has been used in the
European municipal water industry for over 100 years. Ozone
treatment is becoming widely used for potable water in North
America--now the most rapidly growing market.
Ozone is one of the strongest commercially available
oxidizers, making it popular for primary disinfection of potable
water as well as for organic removal in wastewater
applications.
Why Use Ultraviolet
Lamps?
UV water purification system provides clean, safe
drinking water, far exceeding Health Department standards for
potable water. Ultra-violet light kills disease-causing
micro-organisms such as ecoli with a 99.9% effectiveness.
Nothing is added to, or taken out of the water!
Ultra Violet UV Water Sterilization technology seeks
to use the same process as nature to provide drinking water that is
completely Safe - Clean - Fresh
In nature, the sun produces
UV rays which have a germicidal effect on disease causing pathogens
in water. When these contaminants are exposed to UV light, they are
rendered harmless and the output water is considered disinfected.
The Term ultraviolet or "UV" light, as it is commonly referred
to, is a proven means of addressing microbiologically contaminated
waters. This simple, safe technology is suitable for both small flow
residential applications as well as large flow commercial projects.
Disinfection, in its literal sense, means
free from infection. The U.S. Environment Protection Agency (EPA)
and World Health Organization (WHO) define water disinfection as
having an absence of the indicator coliform bacteria. Sterilization
implies complete destruction of all forms of life. For practical
purposes, the term sterilizer is used as a generic term to describe
ultraviolet technology.
Ultraviolet is one energy region of
the electromagnetic spectrum which lies between the x-ray region and
the visible region. UV itself lies in the ranges of 200 nanometers
(1 nanometer (nm) = .0000000001 meter) to 390 nanometers. Since
energy levels increase as the wave length increases, x-rays have
more energy than UV and UV has more energy than the visible light
spectrum.
ction of radiant UV energy
must therefore be accomplished through the conversion of electrical
energy. This conversion is accomplished with a low pressure mercury
vapor lamp. UV light is produced as a result of the electron flow
through the ionized mercury vapor between the electrodes of the lamp
(it should be noted that the bluish glow given off by UV lamps is
due to the starter gas inside the lamp and has no germicidal action
itself).
These UV lamps are similar in design to
standard fluorescent lamps with a few notable exceptions. UV lamps
are typically manufactured with "hard glass" quartz as
opposed to "soft glass" found in fluorescent lamps. This
quartz allows for a UV transmittance of over 90% of the radiated
energy. Fluorescent lamps also contain a thin coating of phosphor
inside the lamp which converts the UV to visible light.
Microorganisms encompass a wide variety of
unique structures and can be grouped into five basic groups:
bacteria, virus, fungi, protozoa and algae. In simplistic terms, a
microorganism is made up of the cell wall, cytoplasmic membrane and
the cell's genetic material, nucleic acid. It is this genetic
material or DNA (deoxyribonucleic acid) that is the target for the
UV light. As UV penetrates through the cell wall and cytoplasmic
membrane, it causes a molecular rearrangement of the microorganism's
DNA which thus prevents it from reproducing. if a cell cannot
reproduce, it is considered dead.
Due to individual cell makeup, different
levels of UV energy are required for destruction. UV lamps emit
about 90% of their radiated energy at 253.7 nm, which, by
coincidence, is very close to the peak germicidal effectiveness of
265 nm.
The degree of microbial
destruction is a product of both time, which is the actual
residence, or contact time the water is within the sterilization
chamber; and intensity, which is the amount of energy per unit area
(calculated by dividing the output in watts by the surface area of
the lamp). 'this product of intensity and time is known as the Dose
and is expressed in micro-watt seconds per centimeter squared (µwsec/cm
squared).
Design
The design of an
ultraviolet sterilizer has an extremely important bearing on how the
UV Dose is delivered. As individual UV lamps emit a set amount of
ultraviolet energy, it is important that a system be sized
correctly. Flow rates are the determining factor and must not be
overstated. The size of the reactor chamber is also of extreme
importance since the delivered intensity decreases accordingly per
the square of the distance from the lamp.
Ballast selection must coincide with the
correct operating current of the lamp since a loss in UV intensity
will occur if the lamp is not driven at the correct output. Optional
solid state ballasts offer the advantage of cooler operating
temperatures, smaller space requirements and less weight, all with
consistent power delivery.
Quartz sleeves shield the actual water flow
from the lamp, offer more uniform operating temperatures and allow
for higher energy transmissibility into the water.
The variety of optional features that may be built into the
sterilizers include: UV monitoring devices that measure the actual
UV output at 253.7 nm, solenoid shut-off devices that will stop
water flow in the event of system failure, flow control devices to
properly limit the water flow in the units, audible and visual
alarms (both local and remote) to warn of lamp failures, high
temperature sensors to monitor excessive temperatures in the reactor
chamber or control panel, and hour meters to monitor the running
time of the UV lamps.
Factors Affecting UV
The
effectiveness of a UV system in eliminating microbiological
contamination is directly dependent on the physical qualities of the
influent water supply.
Suspended Solids or particulate matter cause a shielding problem in
which a microbe may japes through the sterilizer without actually
having any direct UV penetration. This shielding can be reduced by
the correct mechanical filtration of at least five microns in size.
Iron / Manganese will cause staining on the lamp or quartz sleeve at
levels as low as 0.03 ppm. of iron and 0.05 ppm of manganese. Proper
pretreatment is required to eliminate this staining problem.
Calcium / Magnesium hardness will allow
scale formation on the lamp or Quartz sleeve. this problem will be
especially magnified during low flow (or no flow) times when the
calcium and magnesium ions tie up with carbonates and sulfates to
form hard scale buildup inside the sterilizer chamber and on the
lamp or sleeve.
Other Absorbing Compounds such as
humic and fumic acids as well as tannins will reduce the amount of
UV energy available to penetrate through the water to affect the
genetic material, the DNA of the molecule.
Additional Factors Affecting
UV
Temperature
is a determining factor. The optimal operating temperature of the UV
lamp must be near 40 deg. C (104 Deg. F). UV levels will fluctuate
with excessively high or low temperature levels. A quartz sleeve is
typically employed to buffer direct lamp - water contact thereby
reducing any temperature fluctuations. A typical method employed in
a system without a quartz sleeve is to engineer the system to take
into account these fluctuations and typically de-rate the regular
flow rate by the corresponding amount.
Advantages Of UV Lights
Advantages of UV lights include:
·
Environmentally friendly, no
dangerous chemicals to handle or store, no problems of overdosing.
·
Low initial capital cost as well
as reduced operating expenses when compared with similar
technologies such as ozone, chlorine, etc.
·
Immediate treatment process, no
need for holding tanks, long retention times, etc.
·
Extremely economical, hundreds
of gallons may be treated for each jenny of operating cost.
·
No chemicals added to the water
supply - no by-products (i.e. chlorine + organics = trihalomerthanes).
·
No change in taste, odor, pH or
conductivity nor the general chemistry of the water.
·
Automatic operation without
special attention or measurement, operator friendly.
·
Simplicity and ease of
maintenance, periodic cleaning (if applicable) and annual lamp
replacement, no moving parts to wear out.
·
No handling of toxic chemicals,
no need for specialized storage requirements, no WHMIS requirements.
·
Easy installation, only two
water connections and a power connection.
·
more effective against viruses
than chlorine.
Compatible
with all other water processes (i.e., RO, filtration, ion exchange,
etc.)
Installation Guidelines
Once
the application has been determined, the placement of the UV unit
should be given special consideration. The sterilizer should be
place as close to the dispersion point as possible. Since UV is a
physical process and has no residual value, it is imperative that
all points of the distribution system after the sterilizer be
chemically "shocked" to ensure that the system is free
from any downstream microbial contamination.
UV units should be installed on the cold
water line before any branch lines. A typical household distribution
system will have a 5 gpm flow rate; however, if the flow rate is in
question, the UV unit should be oversized rather than undersized. As
an added safety precaution, a flow regulating device should be
installed on any sterilizer to ensure that the manufacturer's
recommended rate flow is not exceeded.
The UV sterilizer should be the last
point of treatment. Any pretreatment products should precede the
sterilizer. If the water supply contains Giardia Lamblia (or other
cysts), an alternate mechanical filtration unit (check NSF St. 53
for applicable units) should be installed at the point-of-use after
the UV unit.
The only positive way to determine if the
sterilizer is indeed operating as designed is to obtain
microbiological testing on the water supply. Even though the lamp is
lit and appears to be functioning, factors such as water quality,
lamp life, and actual UV transmission may be affecting the actual UV
output. It is recommended to have the water tested periodically to
ensure you are receiving bacteriologically safe water. it is also
imperative to follow the manufacturer's guidelines on water quality
and operational procedures.
Sources Of Information
http://www.klumphotography.com/gallery/walk1/walk1.html
http://www.dhs.vic.gov.au/phd/hprot/inf_dis/snids95/chapt5.html
http://www.frommers.com/tips/health/health22.html
http://www.gaiabooks.co.uk/authors/tips.html
http://www.healthproducts.cc/wd-facts.htm
http://www.heal-naturally.itgo.com/
http://www.uky.edu/FiscalAffairs/Environmental/ep/water.html
http://www.ect.uga.edu/roi2001/files/foodborne.htm
http://www.rockyhill.org/MIDDLE/MSNewspaper7/Issue7page1.htm
http://www.everpure.com
http://www.barnsteadthermolyne.com/TechSupport_Full.cfm?num=95&tblToUse=tbltechsupport
http://www.osmonics.com/products/page385.htm
http://askthewaterman.com/reverseosmosis.html
|