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Pollution - The CFC Challenge

Reiner Boehme, VP––Engineering, Inter-Continental Hotels and Resorts
Source: Hotels and Restaurants Network Vol.VI Issue 4

            Are you aware of your country's regulations covering ozone depleting refrigerants and the deadlines for phasing them out? What are the priorities, options and the most economic alternatives? Above all, why should you be taking action?

            Apart from the fact that equipment using CFCs will ultimately reduce the value of your property the phase out of CFCs is being driven by:

1.National legislation following various international agreements (i.e. the 
 montreal Protocol)

2.The future availability and cost of CFCs and HCFCs

3.Operating and maintenance costs of existing equipment

4.Sound environmental practice

What is the problem?

            For over 60 years, CFC refrigerants have been the life blood of refrigeration and air conditioning equipment.

            However, it has been proved that CFCs (chlorofluorocarbon), HCFCs (hydrochlorofluorocarbon) collectively know as ODS (ozone depleting substances) are contributing to the depleting of the ozone layer and to warming of the earth's atmosphere.

            Evidence points to these manmade chlorine and bromine compounds as being responsible for the 'ozone holes' – areas of reduced stratospheric ozone concentration – over the polar regions. Recent scientific findings have shown that significant ozone depletion is also apparent over large areas of the northern and southern hemispheres.

            The ozone layer forms a protective shield around the globe, screening us from ultraviolet (UV) light. Too much can cause health problems such as skin cancer and adversely affects the growth of biological life.

            These chlorine compounds also contribute to the 'greenhouse' effect because they absorb infra-red radiation from the earth's surface. This leads to a higher temperature on earth which is being blamed for more rapid melting of ice in the polar regions and glaciers. This contributes to a rise in the sea level which, in turn, causes further disruption to weather patterns.

            Because of their lifespan, even if we stopped releasing CFCs into the atmosphere today, their destructive work would continue for many decades.

International agreements for a CFC-free future

            Concern about ozone depletion led to the Montreal Protocol and the copenhagen, Vienna and London Amendments. The Montreal Protocol specifies the phase out of ODS manufacture and provides a timetable for its achievement.

            The latest version has been signed by 134 countries. Developing nations have a ten year grace period under Article 5. This includes 53 countries and 35 are listed as temporarily operating under this Article. The gradual phase out eliminates CFCs (and HCFCs over a longer period due to their lower environmental impact and the amount of equipment currently in use).

            Global warming was the subject of the December 1997 summit in Kyoto. No change has yet been made to the protocol's phase out dates since then. (This story was written in 1998).

            Political and economic pressures and the importance each country places on the environment are determining factors in the phase out process. Many developed countries have set earlier phase out. However, between 1992 and 1996 India tripled its CFC productions and China increased it six-fold.

            Taking R-22 for example the US, Australia, India, Japan, Brazil, Venezuela, Egypt and others are in dispute with the European Union, which has set tighter schedules. Phase out in the EU is currently set for 2015 compared ;with 2030, and production ;of equipment larger than 150 kw motor size is prohibited after 2000.

Refrigerants are only a part of the story

When evaluating alternative refrigerants to CFCs, it is essential to determine the environmental impact of the equipment itself. A major indirect contributor to global warming are the carbon dioxide emissions from the energy used to operate the equipment. In most case, these indirect greenhouse gas emissions which result form refrigerant released to the atmosphere from leaks or losses during equipment servicing.

            The total combined effect of direct and indirect contributions to global warming is known as the total equivalent warming impact (TEWI). In new equipment, the direct contribution of the refrigerants (through leaks) accounts for only 2% and the indirect for 98% of the total TEWI.

            By practising containment, the global warming potential (GWP) of refrigerants is negligible. For instance, a machine charges with R-134a but with a leak rate of only 0.1% has a far lower TEWI than an absorption chiller using a zero GWP refrigerant.

Refrigerants, alternatives and future options

            Unfortunately, there is no all purpose refrigerant and there is much confusion in the market. Many alternatives are mixtures which appear under different, often meaningless, trade names. For example, R-407C is traded by Dupont as AC9000, while ICI calls it Klea 66, a mixture of R-32, 125 and 134a in the ratio 23/25/52.

            Some refrigerants were only intermediate solutions and will be discontinued, such as R-123. It is not always easy to tell which replacements are HCFCs or HFCs.

So what is the best Choice?

            Current options are limited by both the chemistry and the application. The main criteria in selecting refrigerants are their :

Chemical and physical behavior (stability, corrosivity, performance, pressure etc.)

Efficiency,

Safety (toxicity, asphysiation, flammability)

Availability and costs,

Environmental impact-ozone depleting potential (ODP) and global warming
potential (GWP).

       Any refrigerant selected for long-term use must support and overall system that is safe, economically and environmentally sound. It must reflect
considerations such as new technologies, waste minimisation, containment, energy efficiency and consumer protection R-123 and R-134 a are single compounds (R 100 series). Mixtures of between two and four refrigerants are divided into two major groups.

        Blends which behave as a single refrigerant (assigned the 500 series number).

      The 400 series –– those which evaporate and condense at different temperatures. For this reason they cannot be used in flooded chillers, but are acceptable in reciprocating and screw type chillers or other direct equipment. The majority are blends of various refrigerants, some of which have flammable or toxic properties. Capital letters A,B, or C stand for different proportions of the same blends. Standard ASHRAE 34 provides a uniform rating of refrigerants for toxicity and flammability.

Where is the air conditioning industry moving?

            The first step is containment refrigerant. Which does not leak does no harm.

            Leak rates form low pressure negative chillers have been improved from
15% to 1-2% against previous models.

            Hermetically sealed positive pressure chillers leak only 0.1% compared with 8% in older equipment.

            The top four chiller manufactures have moved to chlorine free R-134a, replacing R12.

            R-134a requires ester-oil for lubrication, which is more expensive and very sensitive to moisture. R-134a is also used in refrigerators, rooftop units and refrigeration compressors.

            Despite its extensive anticipated use, it is estimated that the contribution of R-134a is also used in refrigerators, rooftop units and refrigeration compressors.

            Despite its extensive anticipated use, it is estimated that the contribution of R-134a to global warming will be less than 1% by 2020. In addition to their R-134a products only Trane and York build R-123 centrifugal chillers, replacing R-11. Trane manufactures R-123 machines in the US, while their European branch does not support this route.       

            When leaks ocur, only 10 ppm R-123 are permitted in plant rooms versus 1000 ppm for R-134a because of R-123's slight toxicity. This requires expensive sensors, ventilation and containment.

            R-22 is still very popular and most manufacturers offer the entire equipment range. However, its phase out may be accelerated (the EC, for example, is considering legislation to prohibit use CFCs for maintaining existing systems and HCFCs in new systems).

            Blends, such as R-404A, R-410A and 410B, R-407C etc. are most widely used. Occasional problems with oil degradation are being addressed. Generally, the industry is waiting for better replacements.

            Hydrocarbons such as Butane, Propane, Propylene and Isobutane are applied in small refrigeration equipment (typically 150 grams and larger industrial applications, but are limited in their commercial use. They are goods choice where their is not risk due to their flammability and where local codes permit their use. Ammonia poses a health risk and sulphur dioxide is toxic.

            New absorption chillers are more energy-efficient than older designs. Whenever waste heat is available, such as in co-generation, or where gas is cheaper than electricity, they are preferable.

Implications of the Montreal Protocol

            The phase out of CFCs and HCFCs has considerable impact on the hotel industry.

            A survey conducted at 87 Inter-Continental hotels revealed that we have over 4500 pieces of equipment––mostly chillers, miscellaneous air conditioning equipment, cold rooms and freezers, ice making machines, refrigerators, fire extinguishers and the like. The most widely used refrigerants are R011, R-12, R-22 and occasionally R-502 except where water is used as refrigerant in absorption chillers. In a few years' time, an entire refrigerant charge of R-11 may cost $ 20,000 where it previously cost $ 4,000.

            Chiller manufacturers have dramatically improved the efficiency of their equipment, which justifies replacement of economic reasons alone, especially when operated throughout the year.

            With some simple and sound management practices it will be possible to keep future costs to a minimum.

 

Refrigerant management in hotels-contain, retrofit or replace?

containment = maintenance

            The Montreal Protocol phases out production of CFC refrigerants but (currently) allows the use of stockpiled and recycled CFCs. Equipment can be operated for as long as refrigerant is available (and permitted in hour country). If you are able to reduce your losses to 2% rather than 8-15%, a stock of 150 kg will last 15 years for a typical 500 ton chiller.

            So, the most important step is to minimise leakage from equipment immediately.

          1.        Obtain your local codes and regulations.

          2.        Implement proper procedures for the handling of refrigerants, equipment repairs, recovery techniques, disposal, and storage. Train your refrigerant technicians. Purchase refrigerant recovery and recycling equipment designed for use with multiple CFC and HCFC refrigerants. Recyled refrigerants could be stockpiled.

          3.        Install high efficiency purge units on low pressure chillers only (R11) to reduce excessive losses during normal operation.

          4.        Check for leaks or install a refrigerant leak detection device in plant rooms.

          5.        Prevent the breakdown or possible loss of an entire chiller. Carry out occasional Eddy-current tests on chiller condenser tubes, especially if there is a history of corrosion, deposits or even plugged tubes. When weak tubes fail, you not only lose the entire refrigerant charge but also have a major repair and possibly no satisfactory air conditioning for some time.

Retrofit

            Smaller items of equipment should be retrofitted an converted to non-chlorine based refrigerants whenever major repairs are due. Depending on the phase out dates of your country you may have to speed up converting R-11 and R-12 equipment––even if it is i good condition.

            Large chillers can be retrofitted, but generally lose capacity and efficiency.

            Depending on their age and condition, retrofitting is generally not recommended as the costs may be 40-100% of that  for new equipment and you are still left with the old machine.

            For chillers which are less than ten years old, the best option is containment, and the next best is conversion. Prior to converting, check with the original manufacturer.

Replacement          

            This is the most expensive alternative, but the most economic and environmentally friendly in the long run. Chillers manufactured today are up to 30-40% more energy efficient than those of the past.

 

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